Solar energy paper index
Cation Dopants in Ceria: A Perspective on Current Research and a Case Study Using CeO <sub>2</sub> Aerogels
One-line summary
A solar energy research paper on Cation Dopants in Ceria: A Perspective on Current Research and a Case Study Using CeO <sub>2</sub> Aerogels.
Engineering notes
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Chinese explanation / 中文解读
中文解读待补充:本站会优先为光伏效率、钙钛矿太阳能电池、储能技术、太阳能热利用、BIPV、并网技术等高价值论文补充中文说明。
Original abstract
High Resolution Image Download MS PowerPoint Slide Substitutional or interstitial metal-cation dopants in CeO 2 play key roles in catalytic, sensing, and energy applications. Cation dopants with a valency less than 4+ create charge-compensating oxygen vacancies in the lattice that boost ionic conductivity and act as reactant adsorption/dissociation sites. These cation dopants also modify the optical properties of CeO 2, enabling the normally high-bandgap oxide to more effectively harvest visible light. In this perspective, we highlight the key progress made using dopants in CeO 2 and the challenges that remain. We briefly summarize common roles that cation dopants play in the CeO 2 lattice, including how their speciation and solubility affect materials properties. We also report how the structural and optical properties of CeO 2 aerogels vary when doped with transition metals (Co, Ni) or lanthanides (Y, La, Gd, Tb, Ho, and Er), thereby providing a rare look at the effects of a diverse group of dopants on a single morphologically fixed system.
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