Facile Design of Low-Dimensional, Hybrid Transparent Conductors Achieving Efficient, Scalable All-Solution-Processed Sb-Chalcogenide-Based Semitransparent Solar Cells

Engineering notes

Engineering notes will be added by the Power for Solar editorial team.

Chinese explanation / 中文解读

中文解读待补充：本站会优先为光伏效率、钙钛矿太阳能电池、储能技术、太阳能热利用、BIPV、并网技术等高价值论文补充中文说明。

Original abstract

High Resolution Image Download MS PowerPoint Slide Antimony sulfide (Sb 2 S 3 ), an emerging photovoltaic material, is desirable for efficient, cost-effective solar cells, attributed to its capability to achieve highly crystallized Sb 2 S 3 films by nonvacuum techniques, favoring the design of all-solution-processed photovoltaics. A high-performance Sb 2 S 3 solar cell often constitutes hydrophobic hole-transporting layers, creating a surface energy mismatch with hydrophilic solution-processed, effective transparent conductors (TCs) like silver nanowires (AgNWs). Therefore, the realization of an efficient, all-solution-processed Sb 2 S 3 solar cell remains challenging. Herein, a completely solution-processed Sb 2 S 3 solar cell is achieved by designing an effective AgNW-based TC by intermixing an AgNW solution with 27 vol % poly(3-hexylthiophene) (P3HT). An interaction between isopropyl alcohol, a polar solvent in the AgNW solution, and P3HT results in the aggregation of the polymer, enhancing adhesion between the AgNWs and the glass/FTO/TiO 2 /Sb 2 S 3 /P3HT surface. This technique enables a reduction in the sheet resistance of AgNW-based TCs by 88%. The Sb 2 S 3 -based solar cells with modified AgNW-based TCs provide an efficiency of 2.1% and a consistent open-circuit value of 0.7 V for up-scaled devices. The adaptation of TCs allows the device to work in bifacial mode with a see-through feature, evidenced by an average visible light transmittance of 11.7%. The developed all-solution-processed Sb 2 S 3 -based semitransparent photovoltaics would be advantageous for photovoltaic-integrated product applications.

Links and sources

Comments