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Gel-Synthesized Zirconium Diboride (ZrB <b> <sub>2</sub> </b> ) Powders for All-Solid-State Symmetric and Zinc-Ion Hybrid Supercapacitor
One-line summary
A solar energy research paper on Gel-Synthesized Zirconium Diboride (ZrB <b> <sub>2</sub> </b> ) Powders for All-Solid-State Symmetric and Zinc-Ion Hybrid Supercapacitor.
Engineering notes
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Chinese explanation / 中文解读
中文解读待补充：本站会优先为光伏效率、钙钛矿太阳能电池、储能技术、太阳能热利用、BIPV、并网技术等高价值论文补充中文说明。
Original abstract
High Resolution Image Download MS PowerPoint Slide This study reports the synthesis and electrochemical evaluation of gel-synthesized ZrB 2 for all-solid-state symmetric supercapacitors. The prepared ZrB 2 powders were characterized using XRD, SEM, FTIR, and XPS analyses. Electrochemical performance was tested using cyclic voltammetry (CV) in 1 M Na 2 SO 4 electrolyte in both positive and negative voltage ranges at a wide range of scan rates from 5 to 500 mV/s. Specific capacitances ranged from 18 to 55 F/g in the positive region and 19–73 F/g in the negative region. Dunn's method analysis revealed that pseudocapacitive contributions dominated at low scan rates (80%), while electric double-layer capacitance (EDLC) contributions dominated at high scan rates (70%), indicating hybrid energy storage behavior. A solid-state symmetric supercapacitor cell was assembled using ZrB 2 electrodes with PVA/Na 2 SO 4 gel electrolyte, exhibiting a low internal resistance of 2.79 Ω·cm 2 and an operational voltage of 1.4 V with rectangular CV profiles. Galvanostatic charge–discharge (GCD) tests showed an energy density of 5.0 Wh/kg and a power density of 5600 W/kg at 8 mA cm –2 . The cell exhibited good cyclic stability of 90.7% after 5000 cycles. Additionally, a gel-derived ZrB 2 electrode was successfully applied in a solid-state zinc-ion hybrid supercapacitor configuration, demonstrating a high specific capacity of 230 mAh/g at 0.9 C and excellent reversibility with 87% Coulombic efficiency. These results confirm the versatility of gel-synthesized ZrB 2 for both symmetric and hybrid energy storage systems, making it a promising electrode material for multifunctional solid-state devices.
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