Solar energy paper index
Metal Oxide Clusters in Gas Giant Exoplanet Atmospheres
One-line summary
A solar energy research paper on Metal Oxide Clusters in Gas Giant Exoplanet Atmospheres.
Engineering notes
Engineering notes will be added by the Power for Solar editorial team.
Chinese explanation / 中文解读
中文解读待补充：本站会优先为光伏效率、钙钛矿太阳能电池、储能技术、太阳能热利用、BIPV、并网技术等高价值论文补充中文说明。
Original abstract
This study investigates the thermal stability and absorption of metal oxide clusters in exoplanetary atmospheres. Utilizing our thermochemical data, we analyze eight distinct cluster families: magnesium oxide (MgO), silicon monoxide (SiO), titanium monoxide (TiO), vanadium monoxide (VO), titanium dioxide (TiO$_2$), vanadium dioxide (VO$_2$), aluminum oxide (Al$_2$O$_3$), and vanadium pentoxide (V$_2$O$_5$). Equilibrium cluster populations as a function of gas temperature and pressure reveal distinct stability regimes. Under solar elemental abundances, (TiO$_2$)$\rm\rm_N$ and (Al$_2$O$_3$)$\rm_N$ are favored at higher temperatures, while (MgO)$\rm_N$ and (SiO)$\rm_N$ dominate at lower temperatures. Computed absorption spectra exhibit strong size- and composition-dependent absorption features in the mid-infrared (8--50~$μ$m), many of which fall within the wavelength range accessible to \texttt{JWST/MIRI}. We further coupled cluster thermodynamics with 3D general circulation model (GCM) outputs to investigate the cluster stability across the ultra-hot Jupiters (UHJs) WASP-121 b and WASP-18 b, the hot Jupiter (HJ) WASP-39 b, and the warm Jupiter (WJ) WASP-69 b. In WASP-121 b and WASP-18 b, extreme dayside temperatures suppress large-cluster stability, yielding atmospheres dominated by metal ions at low pressures and neutral metals at depth, with limited cluster survival on the nightside and morning terminator. In WASP-39 b, larger clusters are not thermochemically favoured despite the enhanced metallicity; instead, equilibrium chemistry stabilises smaller species, with only TiO showing a tendency toward stable larger cluster forms, likely due to its open d-orbitals. In contrast, WASP-69 b favors the formation of larger metal oxide clusters across an extended pressure range, highlighting WJs as a favorable environment for metal oxide cluster stability.
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