Solar energy paper index
Polyiodides of L-ornithine. Discovery of a symmetric(L-Orn(H)-H-L-OrnH) (3+)-cation
One-line summary
A solar energy research paper on Polyiodides of L-ornithine. Discovery of a symmetric(L-Orn(H)-H-L-OrnH) (3+)-cation.
Engineering notes
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Chinese explanation / 中文解读
中文解读待补充：本站会优先为光伏效率、钙钛矿太阳能电池、储能技术、太阳能热利用、BIPV、并网技术等高价值论文补充中文说明。
Original abstract
Two polyiodides of l-ornithine, (l-OrnH2)(I3)(I)(I2) (I) and (l-Orn(H)-H-l-OrnH)(I3)3·4H2O (II) have been synthesized and characterized structurally, by IR, Raman and UV-Vis spectroscopy. Electronic structures of both were determined by quantum chemical calculation based on their structures and bandgaps were measured experimentally as well. Salt (I) is triclinic, space group P1 with two formula units in the unit cell, salt (II) crystallizes in the monoclinic space group C2 with half of formula unit in the asymmetric unit. A symmetric dimeric cation (l-Orn(H)-H-l-OrnH) was observed in the structure of (II) for the first time.
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