Solar energy paper index
Precursor-Stage Electronic and Stacking-Coherence Modulation of Layered PbI <sub>2</sub> via In Situ Ti <sub>3</sub> C <sub>2</sub> T <sub> <i>x</i> </sub> MXene Incorporation
One-line summary
A solar energy research paper on Precursor-Stage Electronic and Stacking-Coherence Modulation of Layered PbI <sub>2</sub> via In Situ Ti <sub>3</sub> C <sub>2</sub> T <sub> <i>x</i> </sub> MXene Incorporation.
Engineering notes
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Chinese explanation / 中文解读
中文解读待补充：本站会优先为光伏效率、钙钛矿太阳能电池、储能技术、太阳能热利用、BIPV、并网技术等高价值论文补充中文说明。
Original abstract
High Resolution Image Download MS PowerPoint Slide MXene composite thin films, PbI 2 –Ti 3 C 2 T x, were fabricated by sequential dynamic spin-coating using a water/ethanol precursor system that enables in situ MXene incorporation while avoiding strongly coordinating solvents. This study addresses a central gap in halide precursor engineering: PbI 2 is commonly treated as a transient phase before perovskite conversion, although its local structure and electronic environment can influence subsequent material formation. Here, we show that Ti 3 C 2 T x incorporation modifies PbI 2 at the precursor level without disrupting the 2H–PbI 2 framework. Profilometry shows that the average film thickness remains nearly constant across the composition series, whereas roughness and surface morphology evolve with MXene loading. Scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS) identifies Ti-rich clustered regions associated with Pb–I-containing material, supporting a growth-mediated incorporation pathway. X-ray diffraction confirms preservation of the 2H structure, while the PbI 2 (001) basal-envelope line shape evolves with composition, consistent with changes in stacking-related environments. Raman spectroscopy shows preservation of the PbI 2 vibrational fingerprint together with mode-selective perturbations. X-ray photoelectron spectroscopy (XPS) reveals statistically significant changes in the Pb 4f-I 3d core-level separation, indicating modification of the local Pb–I electrostatic and chemical environment rather than uniform charging or oxidation-state transformation. Optical measurements show a preserved absorption edge, while photoluminescence quenching and photoelectrical response indicate MXene-associated interfacial deactivation and carrier redistribution. Together, these results show that PbI 2 can be treated as an engineerable precursor whose local morphology, stacking-related order, and electronic environment can be tuned before conversion into perovskite.
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